1.Preheat oven to 180ºC (160ºC fan forced). Grease deep 20cm (8 inch) round cake pan, line base and side with baking paper.
2.Combine butter and chocolate in medium saucepan, stir over low heat until smooth. Transfer to large bowl, cool 10 minutes.
3.Add sifted flour, sugar, eggs, rind, juice and liqueur to chocolate mixture, beat on low speed with electric mixer until ingredients are combined. Increase speed to medium, beat about 2 minutes or until mixture is smooth and paler in colour.
4.Pour mixture into pan, bake about 1 hour. Stand cake in pan 5 minutes before turning, top-side up, onto wire rack to cool.
5.Make choc-orange ganache. Combine chocolate and rind in medium bowl. Bring cream to the boil in small saucepan. Pour hot cream over chocolate mixture, stir until smooth. Stand 15 minutes or until ganache is spreadable.
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